Title :
Identification of Gas-Phase By-Products Formed During Electrical Discharges in Liquid Fuels
Author :
Thagard, Selma Mededovic ; Prieto, Graciela ; Takashima, Kazunori ; Mizuno, Akira
Author_Institution :
Clarkson Univ., Potsdam, NY, USA
Abstract :
In this paper, a plasma-assisted reforming of liquid fuels using a streamer-like electrical discharge was carried out. The main objective was to study the fundamental chemistry of electrical discharges in liquid ethanol, hexadecane, and iso-octane and identify the by-products formed by the dissociation of these molecules. The results have shown that the electrical discharge in all three liquids yields a wide variety of by-products including hydrogen, methane, acetylene, ethylene, propene, butadiene, and ethane. Additionally, the discharge in ethanol results in the formation of carbon monoxide and carbon dioxide.
Keywords :
discharges (electric); dissociation; organic compounds; plasma chemistry; plasma materials processing; acetylene; butadiene; dissociation; ethane; ethylene; gas-phase by-products; hexadecane; iso-octane; liquid ethanol; liquid fuels; methane; plasma-assisted reforming; propene; streamer-like electrical discharge; Discharges (electric); Ethanol; Hydrocarbons; Hydrogen; Liquids; Plasmas; Production; Electrical discharge; ethanol; hexadecane; hydrogen; iso-octane; liquid fuel;
Journal_Title :
Plasma Science, IEEE Transactions on
DOI :
10.1109/TPS.2012.2208203