Title :
Highly stable hydrogenated amorphous silicon germanium solar cells
Author :
Gordijn, Aad ; Zambrano, Raùl Jimenez ; Rath, Jatindra Kumar ; Schropp, Ruud E.I.
Author_Institution :
Debye Res. Inst., Utrecht Univ., Netherlands
fDate :
5/1/2002 12:00:00 AM
Abstract :
This article shows an optimized a-SiGe:H material that behaves highly stable in solar cells. The a-SiGe:H material is deposited by PECVD with high hydrogen dilution, near the microcrystalline deposition regime. We made various a-SiGe:H single solar cells to optimize the device design. The band gap in the central part of the cell is 1.53 eV. The hydrogen bonding configuration in the a-SiGe:H material suggests the presence of voids, however, the material has no noticeable sign of crystallinity. Light soaking experiments showed that the present single junction a-SiGe:H solar cells are highly stable. After one hour of light soaking, a slight improvement in fill factor is observed and an improvement in carrier collection in the red region is evident from spectral response. The stable a-SiGe:H material is incorporated as the bottom cell of a-Si:H/a-SiGe:H tandem solar cells. Unlike the single junction cell, this tandem cell slightly degrades under light soaking. This is solely the result of degradation of the a-Si:H top layer
Keywords :
Ge-Si alloys; Staebler-Wronski effect; amorphous semiconductors; energy gap; hydrogen; plasma CVD coatings; solar cells; PECVD growth; Si:H-SiGe:H; SiGe:H; a-Si:H/a-SiGe:H tandem solar cell; a-SiGe:H single junction solar cell; band gap; carrier collection; fill factor; hydrogenated amorphous silicon germanium solar cell; light soaking; spectral response; stability; Amorphous silicon; Bonding; Crystalline materials; Crystallization; Degradation; Design optimization; Germanium; Hydrogen; Photonic band gap; Photovoltaic cells;
Journal_Title :
Electron Devices, IEEE Transactions on