• DocumentCode
    1324172
  • Title

    Reaction of electrons with CO2 in nonpolar solvents

  • Author

    Itoh, Kengo ; Tada, Satoshi ; Susami, Shu ; Nishikawa, Masaru

  • Author_Institution
    Dept. of Pure & Appl. Sci., Tokyo Univ., Japan
  • Volume
    26
  • Issue
    4
  • fYear
    1991
  • fDate
    8/1/1991 12:00:00 AM
  • Firstpage
    578
  • Lastpage
    581
  • Abstract
    The attachment and detachment rates for the reaction CO2+e-&lrarr2;CO2- were determined in liquid 2,2-dimethylbutane (DMB) and 2-methylbutane (MB) (isopentane) as a function of temperature. In DMB both forward and reverse rates were measured over the range 14 to 45°C, while in MB only the forward reaction was observed over 0 to -73°C. The rates and equilibrium constants were compared with those determined in other solvents, and the factors which influence these quantities in solutions are discussed
  • Keywords
    carbon compounds; electron attachment; electron detachment; molecular electron impact ionisation; 0 to -73 degC; 14 to 45 degC; 2-methylbutane; CO2; DMB; MB; attachment rate; detachment rates; electron reaction; equilibrium constants; forward rates; isopentane; liquid 2,2-dimethylbutane; nonpolar solvents; reverse rates; Cables; Chemical engineering; Design engineering; Digital multimedia broadcasting; Electrons; Kinetic theory; Physics; Radiation detectors; Solvents; Temperature;
  • fLanguage
    English
  • Journal_Title
    Electrical Insulation, IEEE Transactions on
  • Publisher
    ieee
  • ISSN
    0018-9367
  • Type

    jour

  • DOI
    10.1109/14.83673
  • Filename
    83673
    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=49&DC=1324172