Spectral analysis of the light emitted by streamers in hydrocarbon liquids

This paper presents the results of a spectroscopic study from 200 to 850 nm of the light emitted by streamers initiated in cyclohexane and n-pentane under step voltage in point-plane geometry. Experimental spectra of the light emitted by bush-like and filamentary streamers are composed of the H_α-Balmer line, the C₂ Swan band system and a background continuum. The diagnostic method we used for evaluating rotational and vibrational temperatures of excited C₂ in streamers was first tested on high-pressure corona discharges in nitrogen. For streamers in cyclohexane and n-pentane, it was impossible to determine the rotational temperature of C₂ and consequently the effective temperature of molecules in the streamer. Moreover, we found that vibrational populations of excited C₂ do not follow Boltzmann statistics. This indicates that excitation processes are due to chemical reactions. Electron densities deduced of the Stark broadening of H_α are in the range 4×10 ¹⁶ to 7×10¹⁶ cm^-3 for filamentary streamers and 2 to 6×10¹⁷ cm^-3 during the breakdown phase. For slow bush-like streamers, the electron density is not measurable