Title :
The Study on Thermal Expansion of Sintered Sm
Co
Magnets
Author :
Li, Anhua ; Li, Wei ; Wang, Huijie ; Zhu, Minggang ; Pan, Wei ; Lee, Dong
Author_Institution :
Div. of Functional Mater., Central Iron & Steel Res. Inst., Beijing, China
Abstract :
Sintered Sm2Co17 magnets are widely used in aviation, spaceflight and precision instruments, etc. Thermal expansion coefficients alpha are necessary engineering data for the precision applications of the magnets (alphamacr presents the average thermal expansion coefficient). Here, we report an investigation on thermal expansion of sintered Sm2Co17 magnets. The effects of the substitutions of Gd, Dy, Er, and Pr for Sm on thermal expansion characteristics were discussed, respectively. The thermal expansion characteristics were measured using a NETZSCH DIL 402C thermal dilatometer. alpha// is the thermal expansion coefficient in the c axis and alphaperp is the coefficient in the base plane. All the specimens for each material were cut from the same block. A scanning electronic microscope (SEM) equipped with an energy dispersive X-ray analysis system is employed to observe the microstructure. It shows that the thermal expansion coefficient of Sm2Co17 magnets obviously exhibit anisotropy. The alphaperp is higher than the alpha//. The thermal expansion coefficient (both alpha// and alphaperp) increases and the thermal expansion anisotropy (alphaperp-alpha//) decreases with increasing temperature. The substitutions of heavy-rare earth elements, such as Gd+Dy, and Er decrease alphamacr//, the substitution of Pr for Sm moderately increases alphamacr// . The phenomenon is especially obvious in low-temperature range.
Keywords :
X-ray chemical analysis; aerospace materials; avionics; cobalt alloys; copper alloys; dysprosium alloys; erbium alloys; gadolinium alloys; iron alloys; praseodymium alloys; samarium alloys; scanning electron microscopy; sintering; space vehicles; thermal expansion; zirconium alloys; (Sm0.65Er0.35)(CoFe0.22Cu0.08Zr0.02)7.2; (Sm0.65Gd0.25Dy0.10)(CoFe0.22Cu0.08Zr0.02)7.2; (Sm1-xPrx)(CoFe0.25Cu0.08Zr0.02)7.4; NETZSCH DIL 402C thermal dilatometer; SEM; aviation; energy dispersive X-ray analysis system; heavy-rare earth elements; microstructure; precision instruments; scanning electronic microscope; sintered magnets; spaceflight; thermal expansion coefficients; Anisotropy; Sm$_{2}$Co$_{17}$ magnets; thermal expansion;
Journal_Title :
Magnetics, IEEE Transactions on
DOI :
10.1109/TMAG.2009.2024548