• DocumentCode
    1513109
  • Title

    Influence of chemical composition on the crystalline morphologies of magnetite

  • Author

    Clark, Ted M. ; Evans, B.J.

  • Author_Institution
    Dept. of Chem., Michigan Univ., Ann Arbor, MI, USA
  • Volume
    33
  • Issue
    5
  • fYear
    1997
  • fDate
    9/1/1997 12:00:00 AM
  • Firstpage
    4257
  • Lastpage
    4259
  • Abstract
    Cubic and octahedral magnetite specimens from a variety of localities have been examined to ascertain the influence of chemical composition on their morphology. The presence of cations which favor occupancy of the A site in the magnetite spinel structure is shown to be significant in the formation of cubic magnetite at concentrations of x=0.02 in the formula ZnxFe3-xO4, with unusual order-disorder phenomena accompanying this change in habit
  • Keywords
    Mossbauer effect; chemical structure; crystal morphology; crystal structure; ferrites; minerals; order-disorder transformations; zinc compounds; 57Fe Mossbauer spectrum; A site; Fe3O4; Zn0.02Fe2.08O4; ZnxFe3-xO4; ZnFe2O4; cations; chemical composition; crystalline morphologies; cubic magnetite specimens; habit; magnetite; morphology; octahedral magnetite specimens; spinel structure; unusual order-disorder phenomena; Chemicals; Crystalline materials; Crystallization; Impurities; Magnetic analysis; Morphology; Scanning electron microscopy; Shape; Spectroscopy; Zinc;
  • fLanguage
    English
  • Journal_Title
    Magnetics, IEEE Transactions on
  • Publisher
    ieee
  • ISSN
    0018-9464
  • Type

    jour

  • DOI
    10.1109/20.619728
  • Filename
    619728
    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=49&DC=1513109