Title :
Change of the HTSC harmonic susceptibility properties with electrolytic hydrogen loading using different aqueous solution as LiOH and NaOH
Author :
Tripodi, P. ; Di Gioacchino, D. ; Celani, F. ; Spallone, A. ; Vinko, D.
Author_Institution :
LNF, Ist. Nazionale di Fisica Nucl., Prascati, Italy
fDate :
6/1/1999 12:00:00 AM
Abstract :
The higher harmonics magnetic susceptibilities (/spl chi/=/spl chi//sub i/´+i/spl chi//sub i/´´) of HTSC hydrogen loaded as function of the temperature at 6 G of ac magnetic field amplitude at 107 Hz of frequency have been measured. The samples have been loaded by electrolysis in an aqueous solution using /spl mu/s current pulses at room temperature. The HTSC electrodes have been polarized by short pulse width (1 /spl mu/s) and high peak current (/spl ges/4 A) with a low duty-cycle (10/sup -3/) and a variable repetition rate (1-5 kHz). The hydrogen influence on HTSC (T/sub c/, ac losses) has been measured and the increasing of the superconducting properties, particularly T/sub c/ and J/sub c/, have been found. These effects appear strongly dependent to the loading process and to the stoichiometric ratio H/YBCO. It has been demonstrated that the electrolyte (Li, Na) does not affect the YBCO superconducting properties.
Keywords :
barium compounds; critical current density (superconductivity); electrolysis; high-temperature superconductors; hydrogen; hydrogenation; magnetic susceptibility; stoichiometry; superconducting transition temperature; yttrium compounds; 1 mus; 107 Hz; 20 C; 4 A; 6 G; HTSC harmonic susceptibility properties; J/sub c/; LiOH; NaOH; T/sub c/; YBCO superconducting properties; YBa/sub 2/Cu/sub 3/O/sub 7/; ac losses; ac magnetic field amplitude; aqueous solution; electrolysis; electrolyte; electrolytic hydrogen loading; hydrogen influence; loading process; low duty-cycle; magnetic susceptibilities; repetition rate; stoichiometric ratio; Electrochemical processes; Electrodes; Frequency measurement; Hydrogen; Magnetic field measurement; Magnetic susceptibility; Polarization; Space vector pulse width modulation; Temperature; Yttrium barium copper oxide;
Journal_Title :
Applied Superconductivity, IEEE Transactions on