Determination of Plutonium Isotopic Content by Microcalorimeter Gamma-Ray Spectroscopy

Microcalorimeter detectors provide unprecedented energy resolution for gamma-ray spectroscopy. One application is measuring the isotopic composition of plutonium-bearing samples by non-destructive gamma-ray spectroscopy to support nuclear safeguards and nonproliferation efforts. When measured with conventional high-purity germanium (HPGe) detectors, data from these samples contain significant peak overlaps requiring spectral deconvolution for analysis. The improved energy resolution of the microcalorimeter detector reduces peak overlaps leading to improvement in the statistical error component of the total measurement uncertainty. In this paper, we describe analysis code that was developed for spectral peak fitting and isotopic content determination from microcalorimeter and HPGe data. We apply the code to data collected from several plutonium standards to quantify the improvement of the statistical error derived from the improved energy resolution.