Title :
Crucial processing steps for microcrystalline silicon bottom cells
Author :
Kondo, Michio ; Matsui, Takashi ; Nasuno, Yoshiyuki ; Niikura, Chisato ; Fujibayashi, Takashl ; Sato, Aiko ; Matsuda, Akihisa ; Fujiwara, Hiroyuki
Author_Institution :
Res. Center for Photovoltaics, Nat. Inst. of Adv. Ind. Sci. & Technol., Ibaraki, Japan
Abstract :
In the device processing of microcrystalline silicon bottom cells, a variety of processing steps determining not only the material properties but also the interface properties should be taken into account for higher efficiencies. In particular, since microcrystalline silicon is sensitive to impurity incorporation and its variation of the microstructure, processing window can be much narrower than for amorphous silicon based devices. We have found the advantage of the low processing temperature to overcome the oxygen contamination effects and the boron-induced phenomena. We have found that another important factor to influence the device performance particularly under the high rate deposition conditions is the combination of the high deposition pressure and silane depletion conditions. The advantage of the high-pressure depletion technique is discussed in terms of plasma physics and chemistry and its influence on the material properties. Finally, the optical design of the tandem cell is briefly discussed.
Keywords :
boron; crystal microstructure; elemental semiconductors; impurities; optical design techniques; silicon; solar cells; Si; amorphous silicon based devices; boron-induced phenomena; deposition pressure; impurity incorporation; microcrystalline silicon bottom cells; microstructure; optical design; oxygen contamination effects; silane depletion conditions; Amorphous silicon; Contamination; Impurities; Material properties; Microstructure; Plasma chemistry; Plasma devices; Plasma properties; Plasma temperature; Temperature sensors;
Conference_Titel :
Photovoltaic Specialists Conference, 2005. Conference Record of the Thirty-first IEEE
Print_ISBN :
0-7803-8707-4
DOI :
10.1109/PVSC.2005.1488397