Title :
Investigation into the initial growth parameters of hydrothermally grown zinc oxide nanowires
Author :
Barnett, Chris J. ; Brown, Richard A. ; Jones, Daniel R. ; Tarat, Afshin ; Cobley, Richard J. ; Maffeis, Thierry G G
Author_Institution :
Coll. of Eng., Swansea Univ., Swansea, UK
Abstract :
Zinc oxide nanowires have been synthesized hydrothermally using varying initial growth parameters, namely concentrations of precursors and temperature. SEM was then used to characterize the shape and size of the nanowires. PL was also implemented to examine the effects of altering the growth conditions on the defect band of the zinc oxide nanowires. It was found that growing zinc oxide nanowires using higher concentrations of zinc nitrate synthesized nanowires with larger diameters and that they were more tapered. Growing at higher temperatures resulted in nanowires that were longer but also had a larger defect band. Synthesis does not occur when the growth solution is lower than 55 °C.
Keywords :
II-VI semiconductors; crystal defects; high-temperature effects; nanofabrication; nanowires; photoluminescence; scanning electron microscopy; semiconductor growth; wide band gap semiconductors; zinc compounds; SEM; ZnO; defect band; growth solution; high-temperature effects; hydrothermally grown zinc oxide nanowires; initial growth parameters; photoluminescence; scanning electron microscopy; zinc nitrate; Zinc; Defects; Growth; Hexmethylenetetramine; Nanowires; ZnO;
Conference_Titel :
Nanotechnology (IEEE-NANO), 2012 12th IEEE Conference on
Conference_Location :
Birmingham
Print_ISBN :
978-1-4673-2198-3
DOI :
10.1109/NANO.2012.6321959