Title :
Polysulfone- doped polyaniline composite membranes. synthesis and electrochemical characteristics
Author :
Voicu, S.I. ; Stanciu, N.D. ; Nechifor, A.C. ; Vaireanu, D.I. ; Nechifor, G.
Author_Institution :
Fac. of Appl. Chem. & Mater. Sci., Univ. Politeh. of Bucharest, Bucharest
Abstract :
In order to combine the advantages of polysulfone (PSf) as a membrane material to that of polyaniline as a conductive polymer, one has attempted to obtain novel polysulfone-polyaniline composite membranes by a newly improved technique comparing to the existing ones. The strong point of this technique consists in a phase inversion by immersion precipitation accompanying by chemical reaction followed by the activation of polyaniline with sulfonated beta-cyclodextrine. The above synthesized membranes were structurally characterized using Scanning Electron Microscopy, FT-IR spectroscopy, thermal analysis. The ionic conductivity and electrochemical characteristics were also determined by Electrochemical Impedance Spectroscopy.
Keywords :
Fourier transform spectra; conducting polymers; electrochemical impedance spectroscopy; filled polymers; infrared spectra; ionic conductivity; materials preparation; membranes; precipitation; scanning electron microscopy; thermal analysis; FTIR spectroscopy; beta-cyclodextrine; chemical reaction; conductive polymer; electrochemical characteristics; electrochemical impedance spectroscopy; immersion precipitation; ionic conductivity; phase inversion; polysulfone-doped polyaniline composite membranes; scanning electron microscopy; thermal analysis; Biomembranes; Chemicals; Chemistry; Coagulation; Conducting materials; Electric resistance; Glass; Polymers; Solvents; Thermal resistance; composite membranes; doped polyaniline; electrochemical characteristics; polysulfone;
Conference_Titel :
Semiconductor Conference, 2008. CAS 2008. International
Conference_Location :
Sinaia
Print_ISBN :
978-1-4244-2004-9
DOI :
10.1109/SMICND.2008.4703392