Title :
High efficiency on boron emitter n-type Cz silicon solar cells with industrial process
Author :
Veschetti, Yannick ; Sanzone, Vincent ; Cabal, Raphael ; Brand, Pierre ; Raymond, Gaetan ; Bettinelli, Armand
Author_Institution :
CEA INES, Le Bourget, France
Abstract :
Summary form only given. The fabrication of n-type solar cell using industrial process is presented in this study. The boron emitter was formed using novel diffusion technique with BCl3 precursor and the passivation was made by means of dry oxidation. The influence of the grid coverage ratio on the backside was studied and an optimized value of 5% was found. Efficiencies above 19.0% were obtained on 125PSQ Cz wafers. We also report a independently certified efficiency of 18.7% measured by Callab on a special bifacial chuck. A difference in short-circuit current was observed compared to the use of a full chuck. Stability of the fabricated cell was investigated at 50°C under AM1.5 illumination. After over 100 h exposures, the cell efficiency was improved of 0.2% due to a slight increase in the Voc, leading to a maximum efficiency of 19.3%. Potential improvements in efficiency were presented by means of numerical simulations. The optimization the emitter & BSF profiles should lead to efficiency close to 20%. Finally, small modules of 2×2 cells were fabricated and measured to analyse the evolution of the cell performance at a module level. Losses in FF and current were observed will be analysed in a future work.
Keywords :
boron; diffusion; elemental semiconductors; numerical analysis; oxidation; passivation; short-circuit currents; silicon; solar cells; 125PSQ Cz wafers; AM1.5 illumination; B-Si; BSF profiles; bifacial chuck; boron emitter n-type Cz silicon solar cell fabrication; diffusion technique; dry oxidation; efficiency 0.2 percent; efficiency 18.7 percent; efficiency 19.3 percent; grid coverage ratio; industrial process; numerical simulations; passivation; short-circuit current; temperature 50 degC; time 100 h; Boron; Current measurement; IEEE Xplore; Optimization; Photovoltaic cells; Power system stability; Solar power generation;
Conference_Titel :
Photovoltaic Specialists Conference (PVSC), 2011 37th IEEE
Conference_Location :
Seattle, WA
Print_ISBN :
978-1-4244-9966-3
DOI :
10.1109/PVSC.2011.6186660