Title :
Changes in catalytic properties of substituted and unsubstituted heteropolyacids in conductive polymer matrix
Author :
Lapkowski, M. ; Turek, Wojciech ; Barth, Matthew ; Lefrant, S.
Author_Institution :
Silesian Technical University
Abstract :
Summary form only given. In this paper we reported results of our recent studies of substituted and unsubstituted , molecular dispersed heteropolyacids of Keggin and Dawson structure in conductive polymer matrix. The property of anions of PW/sub 12/O/sub 40/ and P/sub 2/W/sub 18/O/sub 62/ series has been tested. Due to its thermal stability´s and possibilities of acid - base doping the polyaniline has been chopped as a conductive polymer carrier. The kinetic and spectroscopic study has been done. The degradation reaction of isopropanol has been chopped as a good model reaction to show the acid - base and redox properties of heteropolyacids.
Keywords :
Chemistry; Doping; Matrices; Polymers; Semiconductor process modeling; Spectroscopy; Testing; Thermal conductivity; Thermal degradation; Thermal stability;
Conference_Titel :
Science and Technology of Synthetic Metals, 1994. ICSM '94. International Conference on
Conference_Location :
Seoul, Korea
DOI :
10.1109/STSM.1994.834797