• DocumentCode
    1919754
  • Title

    A study on the relationship of phase equilibrium and electromechanical properties in the modified PbTiO3-BiFeO3 system

  • Author

    Lu, Peiwen ; Zheng, Weiye ; Shen, Dawei ; Xue, Wanrong ; Zhao, Meiyu

  • Author_Institution
    Nanjing Inst. of Chem. Technol., China
  • fYear
    1992
  • fDate
    30 Aug-2 Sep 1992
  • Firstpage
    545
  • Lastpage
    547
  • Abstract
    In the modified PbTiO3-BiFeO3 system, there is a morphotropic phase boundary (MPB) between the tetragonal and rhombohedral phases. The electromechanical properties of ceramics with composition near the MPB were examined. It is shown that, when the BiFeO 3 content is within 57.5-60 mol.%, there is a mutation of electromechanical properties in the modified PbTiO3 system, making them similar to those of the PbTiO3-PbZrO3 system. In order to explain this mutation, the microstructure, domain structure, and electron diffraction of samples were observed by scanning electron microscopy (SEM). It was found that the special microstructure, domain structure, and one-dimensional superlattice observed in the samples may be the cause of the excellent electromechanical properties of these ceramics
  • Keywords
    bismuth compounds; ceramics; crystal microstructure; domains; electron diffraction examination of materials; lead compounds; phase equilibrium; piezoelectric materials; scanning electron microscope examination of materials; superlattices; MPB; PbTiO3-BiFeO3 system; SEM; ceramics; domain structure; electromechanical properties; electron diffraction; microstructure; morphotropic phase boundary; mutation; one-dimensional superlattice; phase equilibrium; piezoelectric coefficient; rhombohedral phases; scanning electron microscopy; tetragonal phases; Anisotropic magnetoresistance; Capacitive sensors; Ceramics; Crystallography; Diffraction; Microstructure; Piezoelectric materials; Piezoelectric transducers; Solids; Temperature dependence;
  • fLanguage
    English
  • Publisher
    ieee
  • Conference_Titel
    Applications of Ferroelectrics, 1992. ISAF '92., Proceedings of the Eighth IEEE International Symposium on
  • Conference_Location
    Greenville, SC
  • Print_ISBN
    0-7803-0465-9
  • Type

    conf

  • DOI
    10.1109/ISAF.1992.300570
  • Filename
    300570