DocumentCode :
1921189
Title :
Study on Pt-SnO2/C electrode prepared by Electrostatic Fiberswill for direct ethanol fuel cells
Author :
Xuhong Wang ; Cancan Lv ; Hongjun Ni ; Xuefan Jiang
Author_Institution :
Jiangsu Lab. of Adv. Function Mater., Changshu Inst. of Technol., Changshu, China
Volume :
1
fYear :
2011
fDate :
20-22 May 2011
Firstpage :
703
Lastpage :
707
Abstract :
A carbon supported Pt-SnO2/C catalyst was prepared by hydrothermal method and the preparation process was optimized well. Factor of product in solution of different atomic ratio of Pt-SnO2/C catalyst was evaluated for their effects on ethanol oxidation reaction (EOR). The Pt-SnO2/C electrodes were prepared by Electrostatic Fiberswill technology. Structural and compositional analysis of the nanostructured materials were performed by EDS, XRD, TEM techniques. The active surface area was up 108.405mg·cm-2. The ethanol oxidation reaction was tested in a conventional three-electrode cell.The electrochemical studies include cyclic voltammetry, chronoamperometry and AC impedance at Three-electrode under similar conditions to those of the DEFC. At pH 9, composite catalyst particles of low crystallinity, well dispersed, current density up to 109.6mA/cm2, which the Pt-SnO2/C prepared by platinum tin atomic ratio of 3:1, thus the electrocatalytic activity ethanol oxidation was better, which reached high oxidation peak current density with lower potential.
Keywords :
X-ray chemical analysis; X-ray diffraction; catalysts; direct ethanol fuel cells; electrochemical electrodes; electrostatics; oxidation; platinum; reduction (chemical); tin compounds; transmission electron microscopy; voltammetry (chemical analysis); AC impedance; DEFC; Pt-SnO2-C; TEM technique; XRD technique; catalyst; chronoamperometry; cyclic voltammetry; direct ethanol fuel cell; electrocatalytic activity ethanol oxidation; electrostatic fiberswill technology; ethanol oxidation reaction; hydrothermal method; nanostructured material; Optical fiber testing; Tin; Direct ethanol fuel cells (DEFC); Electrostatic Fiberswill; Pt-SnO2 catalyst; hydrothermal method;
fLanguage :
English
Publisher :
ieee
Conference_Titel :
Materials for Renewable Energy & Environment (ICMREE), 2011 International Conference on
Conference_Location :
Shanghai
Print_ISBN :
978-1-61284-749-8
Type :
conf
DOI :
10.1109/ICMREE.2011.5930906
Filename :
5930906
Link To Document :
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