Title :
Wet-chemical synthesis of the size-controlled BaTiO3 nanoparticles for embedded capacitors
Author :
Enhe Zhang ; Suibin Luo ; Wenhu Yang ; Shuhui Yu ; Rong Sun ; Yubao Zhao
Author_Institution :
Shenzhen Inst. of Adv. Technol., Shenzhen, China
Abstract :
In this work, a simple two-step route has been developed to synthesize ultrafine barium titanate (BaTiO3) with size ranging from 30 nm to 100nm by reacting barium hydroxide with tetrabutyl titanate in mixing solvent. This method facilitates the process-control and the property tailoring of the particles. The effect of 1,4-butylene glycol on hydrolysis rate of tetrabutyl titanate, temperature, solvent ratio between isopropanol and water, the particle size, the crystalline phase have been investigated. The prepared BaTiO3 nanoparticles were characterized using X-ray diffraction and scanning electron microscopy (SEM). The results show that the particle size can be easily tuned by adjusting the ratio of 1, 4-butylene glycol, isopropanol and water in solution. The dielectric behavior of the BaTiO3/PVDF at low frequency show that the interfacial polarization acts as an important role for the high dielectric constant (εr).
Keywords :
X-ray diffraction; barium compounds; capacitors; nanoparticles; particle size; permittivity; scanning electron microscopy; titanium compounds; 1,4-butylene glycol effect; BaTiO3; PVDF; SEM; X-ray diffraction; barium hydroxide; crystalline phase; embedded capacitors; high dielectric constant; hydrolysis rate; interfacial polarization; isopropanol; mixing solvent; particle size; process-control; scanning electron microscopy; size 30 nm to 100 nm; size-controlled nanoparticles; solvent ratio; tetrabutyl titanate; two-step route; wet-chemical synthesis;
Conference_Titel :
Electronic Materials and Packaging (EMAP), 2012 14th International Conference on
Conference_Location :
Lantau Island
Print_ISBN :
978-1-4673-4945-1
Electronic_ISBN :
978-1-4673-4943-7
DOI :
10.1109/EMAP.2012.6507898