INVESTIGATION OF NANOSTRUCTURED METAL/POLYMER INTERFACES BY SURFACE ENHANCED RAMAN SCATTERING

Author

Giorgetti, E. ; Muniz-Miranda, M. ; Alloisio, M. ; Dellepiane, G. ; Giusti, A. ; Cuniberti, C. ; Margheri, G.

Author_Institution

Ist. dei Sistemi Complessi, INSTM, Sesto Fiorentino

fYear

2006

fDate

7-10 Nov. 2006

Firstpage

8

Lastpage

12

Abstract

Surface Enhanced Raman Scattering (SERS) experiments were performed on different interfaces consisting of nanostructured metals and ultra-thin layers of conjugated polymers. The Raman electromagnetic enhancement ensured by the surface roughness of different metals (Au, Ag or Al) permitted the monitoring of the optical and spectroscopic properties of ultra-thin polymer layers. In particular, in the case of a novel carbazolyldiacetylene deposited by self assembling on rough silver films or used as a capping agent for gold nanoparticles and subsequently polymerized by UV radiation, SERS experiments permitted detection of two polymer phases, characterized by a different degree of order in the polymer backbone: the highly conjugated blue phase and the less-extended red conformation.

Keywords

aluminium; conducting polymers; gold; interface phenomena; metallic thin films; nanoparticles; polymer films; polymerisation; self-assembly; silver; surface enhanced Raman scattering; surface roughness; ultraviolet radiation effects; Ag; Al; Au; SERS; UV radiation; carbazolyldiacetylene; conjugated polymers; gold nanoparticles; nanostructured metal-polymer interfaces; nanostructured metals; optical properties; polymerization; rough silver films; self assembly; spectroscopic properties; surface enhanced Raman scattering; surface roughness; ultra-thin polymer layers; Gold; Monitoring; Optical films; Optical polymers; Optical scattering; Polymer films; Raman scattering; Rough surfaces; Spectroscopy; Surface roughness;

fLanguage

English

Publisher

ieee

Conference_Titel

Electronics and Photonics, 2006. MEP 2006. Multiconference on

Conference_Location

Guanajuato

Print_ISBN

1-4244-0627-7

Electronic_ISBN

1-4244-0628-5

Type

conf

DOI

10.1109/MEP.2006.335614

Filename

4135698