• DocumentCode
    2249035
  • Title

    Probing Local Structure of Ionic Liquids with Picosecond Time-resolved Raman Spectroscopy

  • Author

    Iwata, Keiji ; Yoshida, Kyosuke ; Hamaguchi, Hiro-o

  • Author_Institution
    Res. Centre for Spectrochemistry, Univ. of Tokyo, Tokyo
  • fYear
    2007
  • fDate
    26-31 Aug. 2007
  • Firstpage
    1
  • Lastpage
    2
  • Abstract
    Vibrational cooling kinetics of the first excited singlet (S1) state of trans-stilbene in ionic liquids was measured with picosecond time-resolved Raman spectroscopy. There was no correlation observed between the cooling rate and the thermal diffusivity of the solvent, suggesting the presence of local structures in the ionic liquids.
  • Keywords
    Raman spectra; cooling; excited states; liquid structure; organic compounds; thermal diffusivity; time resolved spectra; vibrational modes; cooling rate; excited singlet state; ionic liquids; local structures; picosecond time-resolved Raman spectroscopy; solvent; thermal diffusivity; transstilbene; vibrational cooling kinetics; Electronics cooling; Energy exchange; Heat transfer; Kinetic theory; Liquids; Microscopy; Raman scattering; Solvents; Spectroscopy; Vibration measurement;
  • fLanguage
    English
  • Publisher
    ieee
  • Conference_Titel
    Lasers and Electro-Optics - Pacific Rim, 2007. CLEO/Pacific Rim 2007. Conference on
  • Conference_Location
    Seoul
  • Print_ISBN
    978-1-4244-1173-3
  • Electronic_ISBN
    978-1-4244-1174-0
  • Type

    conf

  • DOI
    10.1109/CLEOPR.2007.4391610
  • Filename
    4391610