Title :
Effect of antioxidants on thermal degradation of EPDM and XLPE
Author :
Suenaga, Takashi ; Noguchi, Kazuo ; Okamoto, Yoshio ; Sekii, Yasuo ; Miyake, Koujiro
Author_Institution :
Chiba Inst. of Technol., Narashino
Abstract :
An experimental investigation of the effects of antioxidants on thermal degradation of EPDM and XLPE was carried out. We used ldquomapping methodrdquo in our FTIR spectroscopy to evaluate the degree of thermal degradation. The obtained absorbance data of FT-IR spectra were analyzed statistically. Thereby, we confirmed a clear suppressive effect of sulfur-containing phenolic antioxidant, 4-4 thiobis (3methyl-6-tert-butyl phenol), for thermal degradation of EPDM and XLPE. We confirmed also that a similar effect is obtainable when a phenolic antioxidant is combined with a sulfur type antioxidant. In our experiment, we discovered a great difference of antioxidant effects between EPDM and XLPE. Based on the results of experiments, the scheme of suppressive effects of antioxidant on thermal degradation was discussed.
Keywords :
Fourier transform spectroscopy; XLPE insulation; ethylene-propylene rubber; infrared spectroscopy; EPDM; FTIR spectroscopy; XLPE; mapping method; sulfur-containing phenolic antioxidant; thermal degradation; Aging; Area measurement; Cable insulation; Cables; Infrared spectra; Optical microscopy; Ovens; Resins; Spectroscopy; Thermal degradation; Antioxidant; EPDM; FT-IR; Gel fraction; Infrared microscope; Synergy effect; Thermal degradation; XLPE;
Conference_Titel :
Condition Monitoring and Diagnosis, 2008. CMD 2008. International Conference on
Conference_Location :
Beijing
Print_ISBN :
978-1-4244-1621-9
Electronic_ISBN :
978-1-4244-1622-6
DOI :
10.1109/CMD.2008.4580285