Title :
Hydrogen sulfide in VRLA cells
Author :
Vanasse, H.A. ; Vaccaro, F.J. ; Nikolov, V.R.
Author_Institution :
Philadelphia Sci., PA, USA
Abstract :
This investigation of hydrogen sulfide (H 2S) in VRLA cells produced three major results. First, VRLA cells produce significant amounts of H 2S even at normal float voltages. Second, the lead dioxide in the positive plates absorbs much of this H 2S. Third, this "H 2S cycle" in VRLA cells results in an equilibrium concentration level of no more than 1 ppm of H 2S in the gas space of a typical cell. The data further suggests that even this low amount may decline over time.
Keywords :
adsorption; cathodes; electrochemical electrodes; hydrogen compounds; lead acid batteries; H/sub 2/S; H/sub 2/S absorption; H/sub 2/S production; Pb; Pb-acid valve regulated batteries; PbO/sub 2/; VRLA cells; equilibrium concentration level; lead dioxide; positive plates;
Conference_Titel :
Telecommunications Energy Conference, 2001. INTELEC 2001. Twenty-Third International
Conference_Location :
Edinburgh, UK
Print_ISBN :
0-85296-744-6
DOI :
10.1049/cp:20010606