Title :
Synthesis and characterization of Perovskites based oxides for solid oxides fuel cells materials
Author :
Ismunandar ; Prijamboedi, B. ; Sari, N.R. ; Nursanto, A.
Author_Institution :
Inorg. & Phys. Chem. Div., Inst. Teknol. Bandung, Bandung
Abstract :
Double perovskite structure with composition of Sr2Mg1-xMnxMoO6 (SMMMO) and Sr2Mg1-xFexMoO6 (SMFMO) for anode materials in solid oxide fuel cell have been synthesized by means of solid state reaction and sol gel method, respectively. Crystal structure of those materials were characterized by X-ray diffraction technique and refined using Rietveld method implemented in the Rietica program and their conductivity were determined by DC conductivity measurement technique. The higher Mn concentration the lower the cell volume of SMMO, whilst for SMFO the higher Fe content the larger the cell. For SMMO the ionic conductivity tends to increase with increased Mn, whilst for SMFMO conductivity decreases as Fe concentration increases.
Keywords :
X-ray diffraction; anodes; crystal structure; electrochemical electrodes; iron compounds; manganese compounds; solid oxide fuel cells; strontium compounds; DC conductivity measurement technique; Perovskites based oxides; Rietica program; Rietveld method; Sr2Mg1-xFexMoO6; Sr2Mg1-xMnxMoO6; X-ray diffraction technique; anode materials; ionic conductivity; iron concentration; manganese concentration; sol gel method; solid oxide fuel cell materials; solid state reaction; Anodes; Composite materials; Conducting materials; Conductivity; Crystalline materials; Fuel cells; Iron; Solid state circuits; Strontium; X-ray diffraction;
Conference_Titel :
Sustainable Energy Technologies, 2008. ICSET 2008. IEEE International Conference on
Conference_Location :
Singapore
Print_ISBN :
978-1-4244-1887-9
Electronic_ISBN :
978-1-4244-1888-6
DOI :
10.1109/ICSET.2008.4747057