The effect of molecular orientation on electrical conductivity of liquids with bound water

Dielectric constant ε_s and electrical conductivity of dielectric liquids dissolved water have been studied from a view point of effects of functional group binding water molecules. In this experiment, the aromatic liquids such as a nitrobenzene are used. From the results, it is found that in the case of dielectric liquids binding the electron acceptor base and also dissolving the bound water, the ε_s and the conductivity of liquids become very high but the conductivity is independent of ε_s, and that in the case of liquids with the electron donor base, the conductivity increases with ε_s but its value is smaller than that with electron acceptor