Title :
Interfacial effects in polymer nanocomposites studied by dielectric and thermal techniques
Author :
Pissis, P. ; Klonos, P. ; Kyritsis, A.
Author_Institution :
Dept. of Phys., Nat. Tech. Univ. of Athens, Athens, Greece
Abstract :
DSC and dielectric DRS and TSDC measurements in PDMS/silica and PDMS/titania nanocomposites reveal the presence of several contributions to segmental dynamics and the corresponding glass transition. Further work is needed to clarify as to whether this behavior is common to rubber nanocomposites, in relation to the high flexibility of the polymer backbone.
Keywords :
calorimetry; dielectric relaxation; glass transition; nanocomposites; polymers; PDMS-silica nanocomposites; PDMS-titania nanocomposites; dielectric relaxation spectroscopy; glass transition; interfacial effects; polymer backbone; polymer nanocomposites; segmental dynamics; thermally stimulated depolarization calorimetry; Annealing; Glass;
Conference_Titel :
Electrets (ISE), 2011 14th International Symposium on
Conference_Location :
Montpellier
Print_ISBN :
978-1-4577-1023-0
DOI :
10.1109/ISE.2011.6084985