DocumentCode :
2428409
Title :
The known fluorocarbon materials and future possibilities in the fluorocarbon-lithium power sources
Author :
Mitkin, Valentin N.
Author_Institution :
Inst. of Inorg. Chem., Acad. of Sci., Novosibirsk, Russia
fYear :
1998
fDate :
13-16 Jan 1998
Firstpage :
419
Lastpage :
422
Abstract :
The value of the standard formation enthalpy of all different natures of CFx samples of fluorocarbons CFx(sol) has been calculated statistically from all experimental series and found to be equal to 48.52±1.63 kcal/mol. It is shown that the novel superstoichiometrical fluorocarbon of the general formula CF1.18-1.33 is the most common fluorocarbon semi-industrial material in existence today. Its application in lithium cells gives a maximum theoretical electrical capacity close to 900 mAhrs/g. The theoretical estimations shows that extreme achievable discharge current density of a Li-cell made from hybrid cathodes on a low-temperature dicarbon monofluoride basis with “liquid cathodes”
Keywords :
carbon compounds; cathodes; electrochemical electrodes; electrochemistry; electrolytes; lithium; secondary cells; 2.7 V; Li-CF; Li-CF batteries; discharge current density; electrical capacity; fluorocarbon materials; formation enthalpy; liquid cathodes; power sources; Cathodes; Chemical elements; Chemical industry; Chemistry; Estimation theory; Explosions; Hydrogen; Lithium; Organic materials; Safety;
fLanguage :
English
Publisher :
ieee
Conference_Titel :
Battery Conference on Applications and Advances, 1998., The Thirteenth Annual
Conference_Location :
Long Beach, CA
ISSN :
1089-8182
Print_ISBN :
0-7803-4098-1
Type :
conf
DOI :
10.1109/BCAA.1998.653907
Filename :
653907
Link To Document :
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