Title :
On S/sub 2/F/sub 10/ formation in spark breakdown of SF/sub 6/
Author :
Sauers, I. ; Votaw, P.C. ; Griffin, G.D. ; Kurka, K. ; Easterly, C.E.
Author_Institution :
Oak Ridge Nat. Lab., TN, USA
Abstract :
The authors report on the gas chromatographic (GC) analyses of sparked SF/sub 6/ and the comparison with the analyses of 0.5% S/sub 2/F/sub 10//SF/sub 6/ mixtures. Under the GC conditions used, a peak is observed at elution times identical (to within 0.8%) to the S/sub 2/F/sub 10/ peak in the S/sub 2/F/sub 10//SF/sub 6/ samples. Measurements made on SO/sub 2//SF/sub 2//SF/sub 6/ mixtures indicate that SO/sub 2/ elutes from the column at times extremely close to but slightly longer (by 10%) than what is believed to be the S/sub 2/F/sub 10/ peak. Although complete confirmation of the identification of S/sub 2/F/sub 10/ in the sparked SF/sub 6/ samples awaits further measurements by mass spectrometry of the GC effluent, these analyses indicate that S/sub 2/F/sub 10/ is formed in amounts (on the order of hundreds of p.p.m.) consistent with concentrations necessary for producing the toxic effects previously observed.<>
Keywords :
chromatography; electric breakdown of gases; gaseous insulation; sparks; sulphur compounds; S/sub 2/F/sub 10/ formation; SF/sub 6/; SO/sub 2/-SOF/sub 2/-SF/sub 6/ mixtures; elution times; gas chromatography; spark breakdown; toxic effects; Electric breakdown; Government; Hafnium; Helium; Ovens; Protection; Shape; Sparks; Sulfur hexafluoride; Temperature;
Conference_Titel :
Electrical Insulation, 1988., Conference Record of the 1988 IEEE International Symposium on
Conference_Location :
Cambridge, MA, USA
DOI :
10.1109/ELINSL.1988.13881