Author :
Liu, Qi-Mei ; Peng, Wan-Xi ; Wu, Yan-Xu ; Xie, Xiao-Min ; Guang, Xian-Song
Author_Institution :
Inst. of Rheological Mech. & Mater. Eng., Central South Univ. of Forestry & Technol., Changsha, China
Abstract :
The production of noble Eucalyptus oil from Eucalyptus leaves brings a mass of extracting wastewater pollutive to water environment. In order to better utilize and recover the productive wastewater from the Eucalyptus oil, we used pyrolysis-GC/MS to analyze the possible top value-added components of benzene/ethanol extractives of leaves of two Eucalyptus cultivars, i.e. E. dunnii and E. grandis. Relative content of each component was determined by area normalization. 22 compounds representing 92.12% of the benzene/ethanol extractive of E. dunnii leaves were identified, and the main constituents were 5-(acetylaminomethyl)-4-amino-2-methyl-(15.40%), hexadecanoic acid (10.25%), benzaldehyde,4-hydroxy-(8.64%), xylitol (7.57%), cyclopentanol (7.10%), 2-propenoic acid,3-(4-hydroxyphenyl)-(4.41%), eucalyptol (1.38%), etc. 28 compounds representing 98.41% of the benzene/ethanol extractive of E. grandis leaves were also identified, and the main constituents were ethanol,2-butoxy-(21.70%), benzene,methyl(1-methylethyl)-(15.61%), 17-octadecenal (15.25%), 1-hexacosanal (9.45%), 1-eicosanol (6.92%), cyclotetracosane (6.67%), .alpha.-phellandrene (3.75%), etc. The results of function analyses showed that the benzene/ethanol extractives of leaves of both E. dunnii and E. grandis are abundant in materials of noble natural medicines, and also contains constituents which can be developed into top value-added materials of cosmetic, biofuel and industrial solvent.
Keywords :
biofuel; biomedical materials; cosmetics; crude oil; organic compounds; pyrolysis; solvents (industrial); vegetable oils; wastewater treatment; 1-eicosanol; 1-hexacosanal; 17-octadecenal; 2-butoxy; 2-propenoic acid,3-(4-hydroxyphenyl); 5-(acetylaminomethyl)-4-amino-2-methyl; E. dunnii; E. grandis; Eucalyptus cultivars; alpha-phellandrene; area normalization; benzaldehyde,4-hydroxy; benzene; benzene-ethanol extractives; biofuel material; cosmetic material; cyclopentanol; cyclotetracosane; eucalyptol; eucalyptus leaves; eucalyptus oil; hexadecanoic acid; industrial solvent material; methyl(1-methylethyl); natural medicines; pyrolysis treatment; value-added components; wastewater pollutive; water environment; xylitol; Biofuels; Biological materials; Biomedical materials; Ethanol; Mass production; Oil pollution; Petroleum; Solvents; Wastewater treatment; Water pollution;