Title :
Synthesis and structure of monoclinic bismuth vanadate doped with molybdenum
Author :
Bychkov, K. ; Terebilenko, K. ; Baumer, V. ; Slobodyanik, N.
Author_Institution :
Taras Shevchenko Nat. Univ. of Kyiv, Kiev, Ukraine
Abstract :
The synthetic conditions of BiVO4:Mo crystallization in the molten salts of K-Bi-V-Mo-O have been studied. The compound crystallizes in the monoclinic system, space group I2/a, with unit cell parameters a = 5.1153(3), b = 11.7012(1), c = 5.1878(1) Å, β = 90.24(1)°, Z = 4 representing scheelite-related structure. The formula of the compound established to be Bi0.98V0.95Mo0.05O4.
Keywords :
bismuth compounds; crystal growth from melt; crystal structure; crystallisation; molybdenum compounds; space groups; vanadium compounds; Bi0.98V0.95Mo0.05O4; crystal growth; crystallization; molten salt; monoclinic bismuth vanadate; monoclinic system; scheelite-related structure; space group; Integrated optics; Iterative closest point algorithm; X-Ray single crystal diffraction; crystal growth; flux technique; monoclinic BiVO4;
Conference_Titel :
Oxide Materials for Electronic Engineering (OMEE), 2014 IEEE International Conference on
Conference_Location :
Lviv
Print_ISBN :
978-1-4799-5960-0
DOI :
10.1109/OMEE.2014.6912338
