Title :
Palladium based micromembranes for hydrogen separation and hydrogenation/dehydrogenation reactions
Author :
Franz, A.J. ; Jensen, K.F. ; Schmidt, M.A.
Author_Institution :
Dept. of Chem. Eng., MIT, Cambridge, MA, USA
Abstract :
Novel palladium-based micromembranes have been microfabricated to allow for controlled selective hydrogen flux. These micromembranes have the potential to be used in a variety of hydrogen purification applications, as well as for hydrogenation and dehydrogenation reactions. The microfabrication process allows for integration of heaters and temperature sensors into the device. The e-beam deposited thin Pd film achieves excellent hydrogen selectivity at high permeation rates. The membrane has good mechanical strength and has been shown to withstand pressure gradients of over 5 atm. Microfabricated palladium membranes enable new applications because of their small size, fast thermal response times, and high efficiency.
Keywords :
hydrogen; hydrogenation; membranes; microfluidics; palladium; separation; H/sub 2/; MEMS microfluidics; Pd; Pd film; dehydrogenation reaction; efficiency; electron beam deposition; heater; hydrogen purification; hydrogen selectivity; hydrogen separation; hydrogenation reaction; mechanical strength; microfabrication; palladium micromembrane; permeation rate; pressure gradient; temperature sensor; thermal response time; Biomembranes; Chemical analysis; Chemical technology; Hydrogen; Microfluidics; Micromechanical devices; Palladium; Purification; Silicon; Temperature sensors;
Conference_Titel :
Micro Electro Mechanical Systems, 1999. MEMS '99. Twelfth IEEE International Conference on
Conference_Location :
Orlando, FL, USA
Print_ISBN :
0-7803-5194-0
DOI :
10.1109/MEMSYS.1999.746859