Title :
Alkynyl-ruthenium complexes for nonlinear optical applications
Author :
Sahraoui, B. ; Luc, J. ; Meghea, A. ; Czaplicki, R. ; Fillaut, J.-L. ; Migalska-Zalas, A.
Author_Institution :
Lab. POMA, Univ. of Angers, Angers
Abstract :
Currently, the ruthenium-acetylide organometallic complexes form part of the most studied organometallic compounds in nonlinear optics. We highlight the nonlinear optical properties and the photo-induced structuration of new organometallic complexes containing a ruthenium-acetylide donor fragment able to compete with the strongest organic donors. The experimental studies of third-order nonlinear optical properties of alkynyl-ruthenium complexes are presented. Also we present the dynamics of formation of photo-induced surface relief gratings using a transmission holographic technique and the atomic force microscopy on ruthenium-acetylide complexes containing an azobenzene fragment.
Keywords :
atomic force microscopy; holographic gratings; holography; nonlinear optics; organometallic compounds; atomic force microscopy; azobenzene; nonlinear optical properties; organometallic compounds; photo-induced structuration; photo-induced surface relief gratings; ruthenium-acetylide complexes; ruthenium-acetylide donor fragment; third-order nonlinear optical properties; transmission holography; Atomic force microscopy; Chemical compounds; Gratings; Holographic optical components; Holography; Laboratories; Nonlinear optics; Optical harmonic generation; Optical mixing; Optical surface waves; degenerate four wave mixing; harmonic generation; nonlinear optics; organometallic complexes; ruthenium; surface relief gratings;
Conference_Titel :
Mediterranean Winter, 2008. ICTON-MW 2008. 2nd ICTON
Conference_Location :
Marrakech
Print_ISBN :
978-1-4244-3484-8
Electronic_ISBN :
978-1-4244-3485-5
DOI :
10.1109/ICTONMW.2008.4773092