Title :
VRLA battery temperature concerns other than just thermal runway. I. Practical considerations
Author :
Vaccaro, EJ ; Rhoades, J. ; Le, Arid B.
Author_Institution :
Power Battery Co. Inc., Paterson, NJ, USA
Abstract :
In this paper the effects of temperature on valve-regulated lead-acid (VRLA) battery performance are quantified for the following areas: (1) the capacity-temperature relationship (dC/dT) for discharge rates of 0.17 to 8.0 hours and a temperature range of 30 to 140°F (-1 to 60°C); (2) empirical equations are derived to allow the calculation of dC/dT for most discharge rates; (3) the external surface temperature which best tracks the cell internal temperature during discharge was found to be the container wall surface, parallel to the plates; (4) tests in which the -3 mV/°C coefficient is applied to prevent thermal runaway are shown to cause negative plate self-discharge at temperatures as low as 37°C (99°F); (5) a container wall surface temperature was found to be within 2°C of the internal cell in lift: tests at 50°C (122°F); and (6) experimental results indicated that cell failure due to negative plate self-discharge at 25°C may not be detected in elevated ambient or life test temperatures
Keywords :
electrochemical electrodes; electrochemistry; lead; secondary cells; thermal analysis; -1 to 60 C; 0.17 to 8 h; 122 F; 25 C; 30 to 140 F; 37 C; 50 C; 99 F; Pb; battery performance; discharge rates; electrochemical cell failure; external surface temperature; internal temperature; negative plate self-discharge; temperature concerns; thermal runway; valve-regulated Pb-acid batteries; Automatic testing; Batteries; Chemistry; Containers; Equations; Life testing; Surface discharges; Temperature dependence; Temperature distribution; Voltage;
Conference_Titel :
Telecommunications Energy Conference, 1996. INTELEC '96., 18th International
Conference_Location :
Boston, MA
Print_ISBN :
0-7803-3507-4
DOI :
10.1109/INTLEC.1996.572376