DocumentCode :
2670412
Title :
A novel zinc-air battery for electric vehicles
Author :
Ross, Philip N.
Author_Institution :
Div. of Mater. Sci., Lawrence Berkeley Lab., CA, USA
fYear :
1995
fDate :
10-13 Jan 1995
Firstpage :
131
Lastpage :
133
Abstract :
A new type of zinc electrode is matched with new bifunctional air electrodes to produce a zinc-air battery of a novel design. The zinc electrode is a flow-thru type made from copper foam-metal. The air electrode uses corrosion resistant carbon black as a high area support for a highly dispersed spinel oxide electrocatalyst. The battery design employs flowing electrolyte, 12 M KOH saturated or supersaturated with zincate. Single cells as large as 200 cm2 (1/5 EV design scale) having a capacity of 20 AH have been tested with C/4-C/16 constant current cycling. More extensive and realistic life cycle testing was done with 2 Ah cells, including the Simplified Federal Urban Driving Schedule (SFUDS) cycle. This testing has confirmed that these cells can provide the necessary transient power response required for urban EV applications. The cells achieved an average of 72 SFUDS repetitions (7.2 hrs) per discharge cycle, more than twice the number with a sealed lead acid EV battery in similar testing. The full scale (30 kWh) EV battery design based on these single cell tests indicate an energy density of 90-100 Wh/kg, 60-80 W/kg, and a very low materials cost ($50 per kWh). These results indicate this battery would provide at least twice the vehicle range of a lead acid battery of the same volume at a comparable or even lower materials cost
Keywords :
electric vehicles; electrochemical electrodes; electrolytes; life testing; potassium compounds; secondary cells; zinc; KOH; Simplified Federal Urban Driving Schedule; Zn; bifunctional air electrodes; constant current cycling; copper foam-metal; corrosion resistant carbon black; electric vehicles; energy density; flow-thru Zn electrode; flowing electrolyte; highly dispersed spinel oxide electrocatalyst; life cycle testing; saturated KOH; supersaturated KOH; transient power response; urban electric vehicles; zinc-air battery; Batteries; Copper; Corrosion; Costs; Electric vehicles; Electrodes; Life testing; Materials testing; Resistance; Zinc;
fLanguage :
English
Publisher :
ieee
Conference_Titel :
Battery Conference on Applications and Advances, 1995., Proceedings of the Tenth Annual
Conference_Location :
Long Beach, CA
Print_ISBN :
0-7803-2459-5
Type :
conf
DOI :
10.1109/BCAA.1995.398494
Filename :
398494
Link To Document :
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