Title :
Spectroscopic investigation of new bis(phthalocyaninato)lanthanide complexes for optical limitation of powerful laser radiation
Author :
Savenkova, Natalia S. ; Kuznetsova, R.T. ; Okorokova, Ekaterina V. ; Svetlichnyi, Valeri A. ; Mayer, Georgy V. ; Kalashnikova, Irna P. ; Tomilova, Ludmila G.
Author_Institution :
Tomsk State Univ., Russia
Abstract :
We synthesized and studied sandwich complexes where a lanthanide is coordinated with two phthalocyanine rings. Study of nonlinear optical properties was tested with using the XeCl (308 nm, 10 ns) and second harmonic of Nd:YAG (532 nm, 15 ns) laser. In this experiment were estimated the coefficient of limitation, quantum phototransformation yields and the quantum yield in the triplet state from spectral-luminescent characteristics. Much attention is given to studying of ionic and neutral forms of sandwich complexes in the basic and excited states.
Keywords :
dyes; laser beams; materials testing; optical harmonic generation; optical limiters; optical materials; photoluminescence; triplet state; 10 ns; 15 ns; 308 nm; 532 nm; Nd:YAG laser; XeCl; YAG:Nd; YAl5O12:Nd; basic states; bis(phthalocyaninato)lanthanide complexes; excited states; ionic forms; laser second harmonic; neutral forms; nonlinear optical properties; optical limitation; phthalocyanine rings; powerful laser radiation; quantum phototransformation yields; quantum yield; sandwich complexes; spectral-luminescent characteristics; spectroscopic investigation; triplet state; Absorption; Laser excitation; Nonlinear optics; Optical materials; Optical pulses; Power lasers; Ring lasers; Spectroscopy; State estimation; Testing;
Conference_Titel :
Advanced Optoelectronics and Lasers, 2005. Proceedings of CAOL 2005. Second International Conference on
Print_ISBN :
0-7803-9130-6
DOI :
10.1109/CAOL.2005.1553906
