Influence of lanthanum addition on microstructure and properties of Sn-3.5Ag solder system

The goal of this research is to evaluate the effects of La addition on the microstructure and microhardness of Sn-Ag based solders. Sn-3.5Ag-xLa ternary alloy solder were prepared by adding 0-1.0 wt% La into a Sn-3.5Ag alloy. Copper substrates were then dipped into these solders and aged at 150degC for up to 625 hours. The microstructure and microhardness of the as solidified solder and the aged solder/copper couples were investigated. Experimental results show that Sn-3.5Ag-xLa solders are composed of beta-Sn, Ag₃Sn and LaSn₃ phases, and their microstructure is refined with La addition. After isothermal aging, Ag₃Sn and IMC layer can be effectively depressed by adding a small amount of La element, and the size and amount of LaSn₃ compounds did not change perceptibly with storage time. The addition of La increased the microhardness of the Sn-Ag solder due to the refining effect of Ag₃Sn particles in eutectic and increased formation of LaSn₃ compound. After isothermal storage, the microhardness of solders was decreased with the increasing coarsening of Ag₃Sn compounds as aging time was increased. However, coarsening of Ag₃Sn compounds was retarded by La addition as revealed in this study. Therefore, La addition helped to improve the microhardness and thermal resistance of the solder joints.