• DocumentCode
    2753430
  • Title

    Optical limiting mechanisms of four hexagonal prism-shaped metal cluster compounds

  • Author

    Chang, Cun ; Chu, Zhensheng ; Zhang, Lixin ; Yang, Liu

  • Author_Institution
    Coll. of Electron. Eng., Heilongjiang Univ., Harbin, China
  • fYear
    2010
  • fDate
    July 28 2010-Aug. 1 2010
  • Firstpage
    143
  • Lastpage
    146
  • Abstract
    Optical limiting (OL) mechanisms of hexagonal prism-shaped metal cluster compounds W2Ag4S8 (dppy)4, Mo2Ag4S8(dppy)4, W2Ag4S8(pph3)4 and Mo2Ag4S8(pph3)4 were investigated by time-resolved pump-probe experiment with picosecond laser pulses at 532 nm. Experimental results indicate that dominant OL mechanism for W2Ag4S8 (dppy)4, Mo2Ag4S8(dppy)4 with ligands (dppy)4 is the cooperation of nonlinear absorption and nonlinear scattering. While dominant OL mechanism for W2Ag4S8(pph3)4 and Mo2Ag4S8(pph3)4 with ligands (pph3)4 is nonlinear scattering only. From the analyses of pump-probe experimental results, we can deduce that OL mechanisms for hexagonal prism-shaped metal cluster compounds are related to the ligands of hexagonal prism-shaped metal cluster compounds.
  • Keywords
    absorption coefficients; light scattering; metal clusters; molybdenum compounds; optical limiters; optical pumping; organic compounds; silver compounds; time resolved spectra; tungsten compounds; Mo2Ag4S8(dppy)4; Mo2Ag4S8(pph3)4; W2Ag4S8 (dppy)4; W2Ag4S8(pph3)4; hexagonal prism-shaped metal cluster compounds; ligands; nonlinear absorption; nonlinear scattering; optical limiting; picosecond laser pulses; time-resolved pump-probe experiment; wavelength 532 nm; Compounds; Delay effects; Laser beams; Laser excitation; Metals; Nonlinear optics; Probes; metal cluster; nonlinear absorption; nonlinear scatting; optical limiting;
  • fLanguage
    English
  • Publisher
    ieee
  • Conference_Titel
    Laser Physics and Laser Technologies (RCSLPLT) and 2010 Academic Symposium on Optoelectronics Technology (ASOT), 2010 10th Russian-Chinese Symposium on
  • Conference_Location
    Harbin
  • Print_ISBN
    978-1-4244-5511-9
  • Type

    conf

  • DOI
    10.1109/RCSLPLT.2010.5615377
  • Filename
    5615377