DocumentCode
2753430
Title
Optical limiting mechanisms of four hexagonal prism-shaped metal cluster compounds
Author
Chang, Cun ; Chu, Zhensheng ; Zhang, Lixin ; Yang, Liu
Author_Institution
Coll. of Electron. Eng., Heilongjiang Univ., Harbin, China
fYear
2010
fDate
July 28 2010-Aug. 1 2010
Firstpage
143
Lastpage
146
Abstract
Optical limiting (OL) mechanisms of hexagonal prism-shaped metal cluster compounds W2Ag4S8 (dppy)4, Mo2Ag4S8(dppy)4, W2Ag4S8(pph3)4 and Mo2Ag4S8(pph3)4 were investigated by time-resolved pump-probe experiment with picosecond laser pulses at 532 nm. Experimental results indicate that dominant OL mechanism for W2Ag4S8 (dppy)4, Mo2Ag4S8(dppy)4 with ligands (dppy)4 is the cooperation of nonlinear absorption and nonlinear scattering. While dominant OL mechanism for W2Ag4S8(pph3)4 and Mo2Ag4S8(pph3)4 with ligands (pph3)4 is nonlinear scattering only. From the analyses of pump-probe experimental results, we can deduce that OL mechanisms for hexagonal prism-shaped metal cluster compounds are related to the ligands of hexagonal prism-shaped metal cluster compounds.
Keywords
absorption coefficients; light scattering; metal clusters; molybdenum compounds; optical limiters; optical pumping; organic compounds; silver compounds; time resolved spectra; tungsten compounds; Mo2Ag4S8(dppy)4; Mo2Ag4S8(pph3)4; W2Ag4S8 (dppy)4; W2Ag4S8(pph3)4; hexagonal prism-shaped metal cluster compounds; ligands; nonlinear absorption; nonlinear scattering; optical limiting; picosecond laser pulses; time-resolved pump-probe experiment; wavelength 532 nm; Compounds; Delay effects; Laser beams; Laser excitation; Metals; Nonlinear optics; Probes; metal cluster; nonlinear absorption; nonlinear scatting; optical limiting;
fLanguage
English
Publisher
ieee
Conference_Titel
Laser Physics and Laser Technologies (RCSLPLT) and 2010 Academic Symposium on Optoelectronics Technology (ASOT), 2010 10th Russian-Chinese Symposium on
Conference_Location
Harbin
Print_ISBN
978-1-4244-5511-9
Type
conf
DOI
10.1109/RCSLPLT.2010.5615377
Filename
5615377
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