Title :
Synthesis and evaluation of oleic acid esters as dielectric liquids
Author :
Thomas, P. ; Sridhar, S. ; Krishnaswamy, K.R.
Author_Institution :
Mater. Technol. Div., Central Power Res. Inst., Bangalore, India
Abstract :
The worldwide depletion of petroleum crude and the search for technologically and ecologically alternative to PCBs for transformers has led to the development of synthetic liquid dielectric which are nonflammable, nontoxic and bio-degradable. Esters like methyl oleate and pentaerthritol tetra oleate were synthesised in the laboratory. These esters were evaluated for their physical, chemical, electrical and ageing properties and the values obtained compare well with those of commercially available liquids like Midel 7131 and RTemp fluid. Further accelerated ageing studies were performed on these esters and the data obtained reveal that the esters prepared in the laboratory have very good chemical stability towards oxidation without an inhibitor when compared to Midel 7131 and RTemp fluid which have phenolic inhibitors
Keywords :
ageing; power transformer insulation; transformer oil; Midel 7131; RTemp fluid; ageing properties; bio-degradable; chemical properties; chemical stability; dielectric liquids; electrical properties; methyl oleate; nonflammable; nontoxic; oleic acid esters; oxidation; pentaerthritol tetra oleate; phenolic inhibitors; physical properties; synthetic liquid dielectric; Accelerated aging; Biodegradation; Chemical technology; Dielectric liquids; Inhibitors; Laboratories; Oxidation; Petroleum; Stability; Transformers;
Conference_Titel :
Electrical Insulation, 1996., Conference Record of the 1996 IEEE International Symposium on
Conference_Location :
Montreal, Que.
Print_ISBN :
0-7803-3531-7
DOI :
10.1109/ELINSL.1996.549408