• DocumentCode
    2794981
  • Title

    Reorientation of hydroxide ions in water

  • Author

    Thogersen, J. ; Petersen, C. ; Jensen, S. Knak ; Keiding, S.R.

  • Author_Institution
    Dept. of Chem., Univ. of Aarhus, Aarhus, Denmark
  • fYear
    2009
  • fDate
    14-19 June 2009
  • Firstpage
    1
  • Lastpage
    1
  • Abstract
    The charge transfer was used to solvent (CTTS) transition of OH in water to probe the reorientation of OH ions in water(l-3). The CTTS transition corresponds to an electronic excitation of OH to a quasi-bound state supported by the water molecules in the hydration sphere of the ion.Simultaneously, the hydration sphere itself becomes less attached to the water molecules surrounding it, suggesting that reorientation of OH ions at lower temperatures could involve some degree of dragging its hydration sphere along.
  • Keywords
    charge exchange; solvation; water; CTTS transition; H2O; charge transfer; electronic excitation; hydration sphere; hydroxide ions; quasi-bound state; Anisotropic magnetoresistance; Charge transfer; Chemicals; Chemistry; Optical polarization; Physics; Pulse measurements; Temperature dependence; Temperature measurement; Ultrafast electronics;
  • fLanguage
    English
  • Publisher
    ieee
  • Conference_Titel
    Lasers and Electro-Optics 2009 and the European Quantum Electronics Conference. CLEO Europe - EQEC 2009. European Conference on
  • Conference_Location
    Munich
  • Print_ISBN
    978-1-4244-4079-5
  • Electronic_ISBN
    978-1-4244-4080-1
  • Type

    conf

  • DOI
    10.1109/CLEOE-EQEC.2009.5192558
  • Filename
    5192558
    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=49&DC=2794981