Title :
Photophysical properties of tribranched chromophores Based on 1,3,5-triazine core and 3,4-ethyllenedioxythiophene electron-donating end-groups
Author :
Liu, Li ; Shi, Jie-Ping ; Hu, Hong-Wen ; Lu, Guo-Yuan
Author_Institution :
Dept. of Chem., Nanjing Univ., Nanjing, China
Abstract :
Tribranched chromophores, a 1,3,5-triazine as electron-deficient core, 1,4-phenylenedivinylene as conjugated bridge, 3,4-ethylenedioxythiophene (EDOT) (T1) and triphenylamine (T2) as electron-donating end-groups were successfully prepared. T1 exhibits larger two-photon absorption cross-section than T2, and with an intense blue-shift for λmax in UV, single-photon excited fluorescence (SPEF) and two-photon excited fluorescence (TPEF) spectra.
Keywords :
organic semiconductors; spectral line shift; two-photon spectra; ultraviolet spectra; 1,3,5-triazine electron-deficient core; 3,4-ethyllenedioxythiophene electron-donating end-groups; UV spectra; electron-donating end-groups; intense blue-shift; photophysical properties; single-photon excited fluorescence spectra; tribranched chromophores; two-photon absorption cross-section; two-photon excited fluorescence spectra; Absorption; Argon; Fluorescence; Lasers; Nonlinear optics; Photonics; 3; 4- ethylenedioxythiophene; octupolar chromophores; photophysical properties; triazine; two photon absorption;
Conference_Titel :
Nanoelectronics Conference (INEC), 2011 IEEE 4th International
Conference_Location :
Tao-Yuan
Print_ISBN :
978-1-4577-0379-9
Electronic_ISBN :
2159-3523
DOI :
10.1109/INEC.2011.5991650