Title :
Anisotropy decay of solvated and isolated photofragments
Author :
Blokhin, A.P. ; Gelin, M.F.
Author_Institution :
Inst. of Molecular & Atomic Phys., Acad. of Sci., Minsk, Byelorussia
Abstract :
Summary form only given. After the photolysis of parent molecules, the incipient photoproducts are produced with a nonequilibrium distribution over their angular moments and orientations. the phenomenon has both optical origin (a probability of the absorption and/or emission of light is proportional to the square of the scalar product of light polarization and transition dipole moment) and dynamic origin (the fragments acquire an additional angular momentum due to the rupture of chemical bonds and rotation of the parent molecule).
Keywords :
anisotropic media; high-speed optical techniques; light polarisation; molecular orientation; photolysis; solvation; time resolved spectroscopy; angular moments; angular momentum; anisotropy decay; chemical bonds; dynamic origin; isolated photofragments; light polarization; molecular orientation; nonequilibrium distribution; parent molecule rotation; photolysis; photoproducts; probability; scalar product; solvated photofragments; transition dipole moment; Aerodynamics; Anisotropic magnetoresistance; Atomic beams; Energy states; Large Hadron Collider; Monitoring; Nonlinear dynamical systems; Optical pulse generation; Optical reflection; Spontaneous emission;
Conference_Titel :
Quantum Electronics Conference, 2000. Conference Digest. 2000 International
Conference_Location :
Nice, France
Print_ISBN :
0-7803-6318-3
DOI :
10.1109/IQEC.2000.908040
