Title :
Dielectric energy storage by prepolarized, polymer embedded ferroelectric particles
Author :
Randolf, G. ; Frais-Kölbl, H. ; Hauser, H.
Author_Institution :
Inst. fur Werkstoffe der Elektrotechnik, Tech. Univ. Wien, Austria
Abstract :
In order to maximize the dielectric energy density, the knee of the polarization curve P(E) should coincide with the dielectric strength Es of the material. On the other hand, the efficiency of an energy storage device is also an important parameter. Therefore, hysteresis losses should be small. Two successful possibilities for material optimization have been investigated: embedding the ferroelectric powder in polymers allows one to adjust the permittivity ετ and the polarization curve by modifying the powder/polymer-concentration. The polarization curve is modified and the coercivity EC is minimized by prepolarizing the sample in a bias field EBias, which is acting parallel to the sample plane during the solidification process. The aligned dipoles are then rotated (against the crystal energy) in the direction of the applied field E, which is acting perpendicular to the dielectric plate. In this way the energy density can be increased up to W=106-107 J/m3 to make capacitors replace electro-chemical batteries for ultra quick charging/discharging applications
Keywords :
capacitor storage; dielectric hysteresis; dielectric losses; dielectric polarisation; electric strength; ferroelectric capacitors; filled polymers; particle reinforced composites; permittivity; capacitor energy storage; coercivity; dielectric energy density; dielectric energy storage; dielectric plate; dielectric polarization curve; dielectric strength; energy density; energy storage device; hysteresis losses; permittivity; polymer embedded ferroelectric particles; solidification process; ultra quick charging/discharging; Dielectric breakdown; Dielectric materials; Energy storage; Ferroelectric materials; Hysteresis; Knee; Permittivity; Polarization; Polymers; Powders;
Conference_Titel :
Electrical Insulation and Dielectric Phenomena, 1996., IEEE 1996 Annual Report of the Conference on
Conference_Location :
Millbrae, CA
Print_ISBN :
0-7803-3580-5
DOI :
10.1109/CEIDP.1996.564665