Title :
Thermal conductivity of nano-filled epoxy systems
Author :
Kochetov, R. ; Andritsch, T. ; Lafont, U. ; Morshuis, P.H.F. ; Smit, J.J.
Author_Institution :
Delft Univ. of Technol., Delft, Netherlands
Abstract :
Epoxy resin systems are used in high voltage transformers, cable terminations, bushings, power apparatus, or insulation for X-ray tubes. They could be used more widely, but low thermal conductivity limits their applications. Polymers used as insulating materials generally lack the ability to dissipate excess heat efficiently. The aim of this study is to investigate the influence of different types and filler loadings of electrically insulating-but thermally conductive -nanosized particles on the thermal conductivity of epoxy resin. The concentration of the filler is varied from 0.5 wt.% to 5 wt.%. A combination of ultrasonic processing and high shear force stirring is used to obtain an even dispersion of the corresponding filler in the base material. A silane coupling agent is used for surface functionalization of the nanoparticles. The application of the coupling agent improves the compatibility of the particles with the base polymer. Morphological characteristics of the samples are determined by using transmission electron microscope observation. The composites of epoxy resin containing nanoscale particles showed improved thermal conductivity values compared to epoxy resin without particles. The experimentally measured thermal conductivity results are compared with theoretical and empirical models for two component systems.
Keywords :
filled polymers; nanocomposites; nanoparticles; organic insulating materials; thermal conductivity; transmission electron microscopy; ultrasonic applications; composites; electrical insulation; epoxy resin systems; filler concentration; filler even dispersion; filler loadings; insulating materials; morphological characteristics; nanofilled epoxy systems; nanoparticles; nanoscale particles; particles compatibility; polymers; shear force stirring; silane coupling agent; surface functionalization; thermal conductivity; transmission electron microscope; ultrasonic processing; Cable insulation; Conducting materials; Couplings; Epoxy resins; Insulators; Polymers; Power transformer insulation; Thermal conductivity; Thermal loading; Voltage transformers;
Conference_Titel :
Electrical Insulation and Dielectric Phenomena, 2009. CEIDP '09. IEEE Conference on
Conference_Location :
Virginia Beach, VA
Print_ISBN :
978-1-4244-4557-8
Electronic_ISBN :
0084-9162
DOI :
10.1109/CEIDP.2009.5377801