Title :
Optimization of sythesis conditions of 1,1´ ferrocenedimethanol
Author :
Ming, Chang-xin ; Han, Jian-Rong ; Wang, Wei ; Li, Zhen-chao ; Tian, Xia
Author_Institution :
Coll. of Sci., Hebei Univ. of Sci. & Technol., Shijiazhuang, China
Abstract :
The synthetical conditions of 1,1´-ferrocene-dimethanol were investigated using 1,1´-ferrocenedicarboxylic acid as raw material. The effects of the component ratio, solvent, reaction temperature, time on the product yield have been discussed and the optimum technological conditions have been obtained. using 1,4-dioxane as solvent, the ratio of n(dicarboxylic acid):n(LiAlH4)=1:10, reaction time 4.0h, reaction temperature 90°C, The product yield was 89.9%.
Keywords :
chemical engineering; materials preparation; organometallic compounds; reaction kinetics; solvent effects; 1,1´ ferrocenedimethanol; 1,1´-ferrocenedicarboxylic acid; 1,4-dioxane; component ratio effects; product yield; reaction temperature effects; reaction time effects; solvent effects; sythesis condition optimization; temperature 90 degC; time 4 hr; Aluminum; Compounds; Instruments; Lithium; Materials; Solvents; System-on-a-chip; 1,1´-ferrocenedicarboxylic acid; 1,1´-ferrocenedimetha-nol; LiAlH4; Reduction; Synthesis;
Conference_Titel :
Consumer Electronics, Communications and Networks (CECNet), 2011 International Conference on
Conference_Location :
XianNing
Print_ISBN :
978-1-61284-458-9
DOI :
10.1109/CECNET.2011.5768454
