Title :
Reaction sequence of perovskite formation process in PFW-PFN system by B-site precursor method
Author :
MIN, Kyung Ki ; KIM, Nam Kyoung
Author_Institution :
Dept. of Inorganic Mater. Eng., Kyungpook Nat. Univ., Taegu, South Korea
Abstract :
Reaction sequence of perovskite-phase formation crystallographic properties in the PFW-PFN system are reported. Investigation is focused on the formation of perovskite phase by a “B-site precursor method.” B-site precursors were formed directly from the constituent oxides or through a competition with a pyrochlore-related phase, while perovskite phases were developed through a competition with pyrochlores. Lattice parameters of PFW and PFN were 3.985 and 4.016 Å, respectively
Keywords :
ceramics; crystal structure; ferroelectric materials; lead compounds; sintering; B-site precursor method; PFW-PFN system; PbFe23/W13/O3-PbFe12/Nb12/O 3; PbFeWO3-PbFeNbO3; lattice parameters; perovskite formation process; perovskite-phase formation crystallographic properties; pyrochlore-related phase; reaction sequence; Ceramics; Crystallography; Electronic equipment; Heat treatment; High-K gate dielectrics; Inorganic materials; Lattices; Powders; Temperature; X-ray scattering;
Conference_Titel :
Applications of Ferroelectrics, 1994.ISAF '94., Proceedings of the Ninth IEEE International Symposium on
Conference_Location :
University Park, PA
Print_ISBN :
0-7803-1847-1
DOI :
10.1109/ISAF.1994.522438