Title :
Experimental study on combined deactivating effect of K and Ca on SCR catalysts
Author :
Gao, Feng ; Gao, Xiang ; Fu, Yincheng ; Zhang, Yongxin ; Luo, Zhongyang ; Ni, Mingjiang ; Cen, Kefa
Author_Institution :
State Key Lab. of Clean Energy Utilization, Zhejiang Univ., Hangzhou, China
Abstract :
In order to study the combined deactivating effect of alkaline metals on commercial SCR catalyst, we detected the catalytic performances when potassium and calcium exist simultaneously in flue gas with different proportions. After preparing V/Ti catalyst by the wetness impregnation method, we coated potassium and calcium with different concentrations. The results showed catalysts coated with alkaline metals present an obvious deactivation by contrasting the catalyst performance of VK0Ca0 from 250°C to 350°C. But it seems that there is no obvious relationship between the catalyst performance and the proportions of K2O and CaO. Furthermore, BET, XRD, SEM and EDS were performed to investigate the physical property, crystal phases, surface morphology and chemical composition, respectively.
Keywords :
X-ray chemical analysis; X-ray diffraction; calcium compounds; catalysis; catalysts; chemical engineering; flue gases; potassium compounds; scanning electron microscopy; surface morphology; BET; CaO; K2O; SEM; XRD; alkaline metals; calcium coating; chemical composition; commercial SCR catalyst; deactivating effect; flue gas; potassium coating; selective catalytic reduction technique; surface morphology; temperature 250 degC to 350 degC; wetness impregnation method; Calcium; Chemicals; Surface morphology; Surface treatment; Thyristors; X-ray scattering; SCR; alkaline metals; catalyst deactivation; different proportion;
Conference_Titel :
Electric Information and Control Engineering (ICEICE), 2011 International Conference on
Conference_Location :
Wuhan
Print_ISBN :
978-1-4244-8036-4
DOI :
10.1109/ICEICE.2011.5777326