• DocumentCode
    3274654
  • Title

    Experimental study on combined deactivating effect of K and Ca on SCR catalysts

  • Author

    Gao, Feng ; Gao, Xiang ; Fu, Yincheng ; Zhang, Yongxin ; Luo, Zhongyang ; Ni, Mingjiang ; Cen, Kefa

  • Author_Institution
    State Key Lab. of Clean Energy Utilization, Zhejiang Univ., Hangzhou, China
  • fYear
    2011
  • fDate
    15-17 April 2011
  • Firstpage
    386
  • Lastpage
    389
  • Abstract
    In order to study the combined deactivating effect of alkaline metals on commercial SCR catalyst, we detected the catalytic performances when potassium and calcium exist simultaneously in flue gas with different proportions. After preparing V/Ti catalyst by the wetness impregnation method, we coated potassium and calcium with different concentrations. The results showed catalysts coated with alkaline metals present an obvious deactivation by contrasting the catalyst performance of VK0Ca0 from 250°C to 350°C. But it seems that there is no obvious relationship between the catalyst performance and the proportions of K2O and CaO. Furthermore, BET, XRD, SEM and EDS were performed to investigate the physical property, crystal phases, surface morphology and chemical composition, respectively.
  • Keywords
    X-ray chemical analysis; X-ray diffraction; calcium compounds; catalysis; catalysts; chemical engineering; flue gases; potassium compounds; scanning electron microscopy; surface morphology; BET; CaO; K2O; SEM; XRD; alkaline metals; calcium coating; chemical composition; commercial SCR catalyst; deactivating effect; flue gas; potassium coating; selective catalytic reduction technique; surface morphology; temperature 250 degC to 350 degC; wetness impregnation method; Calcium; Chemicals; Surface morphology; Surface treatment; Thyristors; X-ray scattering; SCR; alkaline metals; catalyst deactivation; different proportion;
  • fLanguage
    English
  • Publisher
    ieee
  • Conference_Titel
    Electric Information and Control Engineering (ICEICE), 2011 International Conference on
  • Conference_Location
    Wuhan
  • Print_ISBN
    978-1-4244-8036-4
  • Type

    conf

  • DOI
    10.1109/ICEICE.2011.5777326
  • Filename
    5777326