Title :
Biosorption of Pb (II) ions using rubber seed coat: equilibrium and kinetic studies
Author :
Senusi, Faraziehan ; Karim, Khairiah Abd
Author_Institution :
Fac. of Chem. Eng., UiTM, Shah Alam, Malaysia
Abstract :
Biosorption of Pb (II) ions on untreated and treated rubber seed coat (RSC) using acid and base pre-treatment in an aqueous solution were investigated. Among the biosorbents, base-treated RSC were capable to remove Pb (II) ions higher than the untreated and acid-treated RSC. The analyses data were fitted well to Langmuir adsorption isotherm model. The kinetic studies were carried out at different initial metal ion concentrations and it was found that the pseudo second order model fitted well to the data by higher correlation coefficient, R2 and the lower value of sum of squares error (SSE). FTIR, SEM and EDX analysis showed the involvement of functional groups and ion exchange mechanism during biosorption process.
Keywords :
adsorption; biotechnology; ions; rubber; Langmuir adsorption isotherm model; aqueous solution; base pre-treatment; base-treated RSC; biosorbents; biosorption process; correlation coefficient; equilibrium study; ion exchange mechanism; kinetic study; metal ion concentration; pseudo second order model; rubber seed coat; Biological system modeling; Data models; Ions; Kinetic theory; Lead; Mathematical model; Biosorption; EDX; Kinetics; Pb (II) ions; Pre-treatment;
Conference_Titel :
Humanities, Science and Engineering (CHUSER), 2011 IEEE Colloquium on
Conference_Location :
Penang
Print_ISBN :
978-1-4673-0021-6
DOI :
10.1109/CHUSER.2011.6163755