Title :
High-efficiency heterojunction solar cells on crystalline silicon and germanium substrates enabled by low-temperature epitaxial growth of silicon
Author :
Hekmatshoar, Bahman ; Shahrjerdi, Davood ; Bedell, Stephen W. ; Sadana, Devendra K.
Author_Institution :
IBM T.J. Watson Res. Center, Yorktown Heights, NY, USA
Abstract :
We demonstrate high-efficiency heterojunction (HJ) solar cells realized by epitaxial growth of thin layers of highly-doped Si on crystalline Si (c-Si) and crystalline Ge (c-Ge) substrates using plasma-enhanced chemical vapor deposition (PECVD) at temperatures as low as 150°C. We have achieved a conversion efficiency of 21.4% on p-type c-Si substrates textured by random pyramids and Al-doped zinc oxide (ZnO:Al) electrodes sputtered at room-temperature. To the best of our knowledge, this is the highest conversion efficiency reported for HJ solar cells on p-type c-Si substrates. We have achieved conversion efficiencies of 5.9% and 6.4% on n-type and p-type c-Ge substrates, respectively, which are comparable with efficiencies reported for conventional c-Ge cells requiring process temperatures up to 600°C.
Keywords :
II-VI semiconductors; aluminium; epitaxial growth; germanium; plasma CVD; semiconductor growth; silicon; solar cells; zinc compounds; Ge; Si; ZnO:Al; conversion efficiency; crystalline silicon; germanium substrates; heterojunction solar cells; low temperature epitaxial growth; plasma enhanced chemical vapor deposition; random pyramids; temperature 150 degC; temperature 293 K to 298 K; temperature 600 degC; Doping; Epitaxial growth; Germanium; Heterojunctions; Photovoltaic cells; Silicon; Substrates; amorphous silicon; epitaxial growth; germanium; heterojunction; photovoltaic cells; silicon;
Conference_Titel :
Photovoltaic Specialists Conference (PVSC), 2012 38th IEEE
Conference_Location :
Austin, TX
Print_ISBN :
978-1-4673-0064-3
DOI :
10.1109/PVSC.2012.6317898