Title :
Accelerating velocity of hydrogen generation from sodium borohydride by citric acid catalyst
Author :
Tomoda, Keisuke ; Hoshi, Nobukazu ; Haruna, Junnosuke ; Cao, Ming ; Yoshizaki, Atsuhiro ; Hirata, Kazufumi
Author_Institution :
Dept. of Electr. Eng., Tokyo Univ. of Sci., Noda, Japan
Abstract :
Sodium borohydride (NaBH4) is attractive as fuel for fuel cell hybrid electric vehicle (FCHEV) because of its high energy density. The authors have proposed and made a hydrogen generation system which uses sodium borohydride as fuel before now. However, as for this system, there has been a problem in the velocity of hydrogen generation under low-temperature water environment. This paper examined citric acid catalyst for improving velocity of hydrogen generation from sodium borohydride under low-temperature water. This paper clarifies that the generation velocity of hydrogen is improved by adding citric acid solution when hydrolyzing sodium borohydride. It was confirmed that there is not much problem in the power generation characteristics of a 100W fuel cell (FC), even if using rapid hydrogen generation system by adding citric acid solution.
Keywords :
catalysts; fuel cell vehicles; hybrid electric vehicles; hydrogen production; sodium compounds; FCHEV; NaBH4; accelerating velocity; citric acid catalyst; fuel cell hybrid electric vehicle; high energy density; hydrogen generation system; hydrolyzing sodium borohydride; power 100 W; sodium borohydride; temperature water environment; Fuel cells; Fuels; Hydrogen; Inductors; Nickel; Prototypes; Water heating; Sodium borohydride; citric acid; fuel cell; fuel cell hybrid electric vehicle; hydrogen;
Conference_Titel :
Renewable Energy Research and Applications (ICRERA), 2012 International Conference on
Conference_Location :
Nagasaki
Print_ISBN :
978-1-4673-2328-4
Electronic_ISBN :
978-1-4673-2329-1
DOI :
10.1109/ICRERA.2012.6477320