Author :
Nogami, T. ; Penny, C. ; Madan, A. ; Parks, C. ; Li, Jie ; Flaitz, P. ; Uedono, Akira ; Chiang, S. ; He, Mengxun ; Simon, A. ; Bolom, T. ; Ryan, Tim ; Ito, Fumihiko ; Christiansen, C. ; Tai, Li-Heng ; Hu, C.-K. ; Kim, Heonhwan ; Zhang, Xiaobing ; Tanwar,
Abstract :
Cu(Mn) alloy seed BEOL studies revealed fundamental insights into Mn segregation and EM enhancement. We found a metallic-state Mn-rich Cu layer under the MnOx layer at the Cu/SiCNH cap interface, and correlated this metallic layer with additional EM enhancement. A carbonyl-based CVD-Co liner film consumed Mn, reducing its segregation and EM benefit, suggesting O-free Co liner films are strategic for Cu-alloy seed extendibility.