DocumentCode
3602268
Title
Investigation of Nano-Molybdenum Carbide Particle Produced by Wire-Explosion Process
Author
Sarathi, Ramanujam ; Reddy, Ravula Sugunakar ; Tavarmani, Rashmi S. ; Okamoto, Akira ; Suematsu, Hisayuki ; Selvam, Parasuraman ; Kamachi Mudali, Uthandi ; Kamaraj, Muthusamy
Author_Institution
Dept. of Electr. Eng., IIT Madras, Chennai, India
Volume
43
Issue
10
fYear
2015
Firstpage
3470
Lastpage
3475
Abstract
Molybdenum carbide (MoC) nanoparticles were generated by exploding molybdenum conductor in methane gas ambience at different pressures. To enhance the level of carburization, exploding conductor was coated with graphite and paraffin mixtures. Various physico-chemical studies were employed to characterize the produced nano-carbide particles, viz., X-ray diffraction, optical emission spectroscopy, X-ray photoelectron spectroscopy, and transmission electron microscopy. It was deduced from these investigations that the nano-MoC particles produced by a wire explosion process (WEP) are spherical in shape. The size of the particles formed by WEP can be controlled by varying the operating ambience pressure of the methane gas. The particle size produced follows a log-normal distribution. Optical emission results clearly indicates the presence of Mo-I, C-I, and C-II components during WEP. X-ray photoelectron spectroscopy confirms the formation of MoC.
Keywords
X-ray diffraction; X-ray photoelectron spectra; mixtures; molybdenum compounds; nanofabrication; nanoparticles; particle size; transmission electron microscopy; MoC; X-ray diffraction; X-ray photoelectron spectroscopy; graphite; methane gas ambience; nanomolybdenum carbide particle; optical emission spectroscopy; paraffin mixtures; particle size; physico-chemical property; transmission electron microscopy; wire-explosion process; Coatings; Conductors; Explosions; Graphite; Nanoparticles; Stimulated emission; Wires; Log-normal distribution; X-ray diffractogram (XRD); X-ray diffractogram (XRD).; nano-molybdenum carbide (MoC); optical emission spectroscopy (OES); transmission electron microscopy (TEM); wire-explosion process (WEP);
fLanguage
English
Journal_Title
Plasma Science, IEEE Transactions on
Publisher
ieee
ISSN
0093-3813
Type
jour
DOI
10.1109/TPS.2015.2426019
Filename
7108044
Link To Document