• DocumentCode
    3602268
  • Title

    Investigation of Nano-Molybdenum Carbide Particle Produced by Wire-Explosion Process

  • Author

    Sarathi, Ramanujam ; Reddy, Ravula Sugunakar ; Tavarmani, Rashmi S. ; Okamoto, Akira ; Suematsu, Hisayuki ; Selvam, Parasuraman ; Kamachi Mudali, Uthandi ; Kamaraj, Muthusamy

  • Author_Institution
    Dept. of Electr. Eng., IIT Madras, Chennai, India
  • Volume
    43
  • Issue
    10
  • fYear
    2015
  • Firstpage
    3470
  • Lastpage
    3475
  • Abstract
    Molybdenum carbide (MoC) nanoparticles were generated by exploding molybdenum conductor in methane gas ambience at different pressures. To enhance the level of carburization, exploding conductor was coated with graphite and paraffin mixtures. Various physico-chemical studies were employed to characterize the produced nano-carbide particles, viz., X-ray diffraction, optical emission spectroscopy, X-ray photoelectron spectroscopy, and transmission electron microscopy. It was deduced from these investigations that the nano-MoC particles produced by a wire explosion process (WEP) are spherical in shape. The size of the particles formed by WEP can be controlled by varying the operating ambience pressure of the methane gas. The particle size produced follows a log-normal distribution. Optical emission results clearly indicates the presence of Mo-I, C-I, and C-II components during WEP. X-ray photoelectron spectroscopy confirms the formation of MoC.
  • Keywords
    X-ray diffraction; X-ray photoelectron spectra; mixtures; molybdenum compounds; nanofabrication; nanoparticles; particle size; transmission electron microscopy; MoC; X-ray diffraction; X-ray photoelectron spectroscopy; graphite; methane gas ambience; nanomolybdenum carbide particle; optical emission spectroscopy; paraffin mixtures; particle size; physico-chemical property; transmission electron microscopy; wire-explosion process; Coatings; Conductors; Explosions; Graphite; Nanoparticles; Stimulated emission; Wires; Log-normal distribution; X-ray diffractogram (XRD); X-ray diffractogram (XRD).; nano-molybdenum carbide (MoC); optical emission spectroscopy (OES); transmission electron microscopy (TEM); wire-explosion process (WEP);
  • fLanguage
    English
  • Journal_Title
    Plasma Science, IEEE Transactions on
  • Publisher
    ieee
  • ISSN
    0093-3813
  • Type

    jour

  • DOI
    10.1109/TPS.2015.2426019
  • Filename
    7108044