Comparative studies of the stability of various fluids under electrical discharge and thermal stresses

It is a well-known fact that the service reliability of power transformers largely depends upon the condition of the dielectric fluid. The steady deterioration (under the influence of the multiple stresses) of the insulation has an important impact on the condition of the transformers themselves. This contribution reports some investigations on some commercially available ester, silicone and mineral oil fluids. Some of their physicochemical properties are studied by submitting them to various stresses: electrical, thermal and oxidation. Many comparisons are made according to the quality test results of mineral oil, as it is very familiar to the transformer industry. A new technique using a reactive free radical reagent, 2,2-diphenyl-1- picrylhydrazyl (DPPH), added to both new oil for reference purposes and different aged oil to assess free radical concentration is presented. The gassing tendency under either thermal or electrical stress, along with the physicochemical properties of the fluids, is affected; it is assessed with the production of oxidative aging by-products. The gassing performance characteristics of natural ester fluids are far superior to those of conventional mineral oil. A significant reduction in insulation aging rate was observed with synthetic ester fluids.