Title :
New Potentiometric Carbon Paste Electrode for Determination of Reactive Yellow 160 Dye Concentration in Textile Wastewater
Author :
Ghalwa, Nasser Abu
Author_Institution :
Chem. Dept., Al Azhar Univ., Gaza, Palestinian Authority
Abstract :
Reactive Yellow 160 (RY 160) dye in real samples was determined by a new modified carbon paste electrode based on RY-Alkyldimethylbezylammoniumchloride as a chemical modifier. The construction, performance, and applications of RY 160 dye carbon paste electrode are described. The best performance was exhibited by the electrode having the paste containing 0.5 wt% ion-exchangers (RY 160), 51 wt% graphite, and 48.5 wt% tributylphosphate. The modified electrode showed a near-Nernstian slope of 14.6±0.5 mV over the concentration range of 4.5×10-7-1.0×10-2 M with the limit of detection 3.1×10-7 over the pH range 3.7-8.1. The proposed sensor revealed good selectivities over a wide variety of anions.
Keywords :
carbon; dyes; electrochemical electrodes; electrochemical sensors; ion exchange; negative ions; textile industry; wastewater; RY 160; RY-Alkyldimethylbezylammoniumchloride; anion; chemical modifier; chemical sensor; graphite; ion exchanger; potentiometric carbon paste electrode; reactive yellow 160 dye concentration determination; textile wastewater; tributylphosphate; Carbon; Electric potential; Electrodes; Graphite; Ions; Powders; Temperature sensors; Ion-selective electrode; carbon paste electrode; potentiometric; reactive yellow 160 dye;
Journal_Title :
Sensors Journal, IEEE
DOI :
10.1109/JSEN.2013.2272720